6‐Amino‐3‐Pyridinols: Towards Diffusion‐Controlled Chain‐Breaking Antioxidants
Angewandte Chemie International Edition2003Vol. 42(36), pp. 4370–4373
Citations Over TimeTop 10% of 2003 papers
Maikel Wijtmans, Derek A. Pratt, Luca Valgimigli, Gino A. DiLabio, Gian Franco Pedulli, Ned A. Porter
Abstract
The incorporation of nitrogen in the phenolic ring leads to compounds with very low phenolic OH bond dissociation enthalpies, and thus high reactivities towards peroxyl radicals, but which are reasonably stable to direct reactions with air. The 3-pyridinols 1 and 2 are extremely effective peroxyl-radical-trapping chain-breaking antioxidants. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z51881_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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