Efficient Diastereoselective Intermolecular Rhodium‐Catalyzed CH Amination
Citations Over TimeTop 10% of 2006 papers
Abstract
Successful matchmaking: The combination of a chiral nitrene precursor with a chiral rhodium(II) catalyst is the key factor that allows efficient intermolecular regioselective CH amination. Good-to-excellent yields and excellent diastereoselectivities can be obtained with a stoichiometric amount of the CH bond containing substrate. nttl=N-1,8-naphthoyl-tert-leucine. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z601248_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Related Papers
- → Catalytic C–H amination: recent progress and future directions(2009)784 cited
- → Combining visible-light induction and copper catalysis for chemo-selective nitrene transfer for late-stage amination of natural products(2022)18 cited
- → Rhodium-Catalyzed Sulfimidation Reactions: A Computational Study(2021)12 cited
- → Catalytic CH Amination with Nitrenes(2007)5 cited
- → Biocatalytic Platform for Intermolecular Propargylic C–H Amination(2022)