A 3D Aluminoborate Open Framework Interpenetrated by 2D Zinc–Amine Coordination‐Polymer Networks in Its 11‐Ring Channels
Angewandte Chemie International Edition2014Vol. 53(28), pp. 7188–7191
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Abstract
A new inorganic-organic hybrid solid, [Zn(dap)2 ][AlB5 O10 ], combining the structural features of 3D open-framework inorganic solids and 2D metal-organic coordination polymers has been synthesized under solvothermal conditions. The compound displays extensive luminescence and moderate second-harmonic-generation efficiency.
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