The synthesis of heterogenous Co‐MOFs and application in the catalytic hydrosilylation of alkenes
Applied Organometallic Chemistry2022Vol. 36(6)
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Abstract
Hydrosilylation employing metal–organic frameworks (MOFs) as the catalyst are promising because of their high catalytic reactivity and sustainability of heterogeneous catalyst. A highly simple and efficient method for the hydrosilylation of olefins catalyzed by an air‐stable MOF‐cobalt catalysts is developed. This approach is featured by 0.1% of Co‐MOFs catalyst with excellent reactivity, recyclability, and good functional group tolerance. The Co‐MOFs can catalyze hydrosilylation of styrene or its derivatives with Ph 2 SiH 2 in the presence of NaBHEt 3 . Moreover, the catalysts we developed show excellent stability, and the activity is not significantly reduced after repeating the cycle for five times.
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