Rate Constants for the Reactions of CH2 (X3B1) with Selected Alkenes at Temperatures Between 296 K≤T≤728 K
Citations Over Time
Abstract
Abstract The kinetics of the reactions of CH 2 (X̄ 3 B 1 ) with selected alkenes R = ethylene (1), tetramethylethylene (2), cycloheptatriene (3), and 1,3‐butadiene (4) were studied at temperatures between 296 K≤ T ≤728 K. Rate constants were measured for reactions (2–4) using the discharge flow technique with Far‐Infrared Laser Magnetic Resonance (FIR–LMR) detection of 3 CH 2 . The experimental data can be described by the rate expressions (±2σ) magnified image These data and results for reaction (1) obtained earlier were analyzed to separate the contributions to the CH 2 (X̄) depletion by reactive channels versus collisional excitation to the ã 1 A 1 state of CH 2 followed by reactions of CH 2 (ã). The rate expressions (±2σ) for the reactive pathways of CH 2 (X̄) were found to be magnified image .
Related Papers
- → The effect of ethylene and short-chain saturated fatty acids on ethylene sensitivity and binding in ripening bananas(1991)22 cited
- → Effects of External Ethylene on the Production of Endogenous Ethylene in Olive Leaf Tissue(1988)7 cited
- Modification of ethylene-induced ripening of 'Hass' avocados by an ethylene absorbing filter(2001)
- Effects of 1-MCP on Fruit Firmness, Respiration and Ethylene Production Induced by Exogenous Ethylene in Nectarine Fruit(2005)
- THE STUDY OF SOME NON-SOLATED RESONANCES FOR THE ~(23)Na (p,α)~(20)Ne REACTION(1979)