Metal‐organic framework‐based single‐atom electro‐/photocatalysts: Synthesis, energy applications, and opportunities
Citations Over TimeTop 10% of 2023 papers
Abstract
Abstract Single‐atom catalysts (SACs) have gained substantial attention because of their exceptional catalytic properties. However, the high surface energy limits their synthesis, thus creating significant challenges for further development. In the last few years, metal–organic frameworks (MOFs) have received significant consideration as ideal candidates for synthesizing SACs due to their tailorable chemistry, tunable morphologies, high porosity, and chemical/thermal stability. From this perspective, this review thoroughly summarizes the previously reported methods and possible future approaches for constructing MOF‐based (MOF‐derived‐supported and MOF‐supported) SACs. Then, MOF‐based SAC's identification techniques are briefly assessed to understand their coordination environments, local electronic structures, spatial distributions, and catalytic/electrochemical reaction mechanisms. This review systematically highlights several photocatalytic and electrocatalytic applications of MOF‐based SACs for energy conversion and storage, including hydrogen evolution reactions, oxygen evolution reactions, O 2 /CO 2 /N 2 reduction reactions, fuel cells, and rechargeable batteries. Some light is also shed on the future development of this highly exciting field by highlighting the advantages and limitations of MOF‐based SACs.
Related Papers
- → Electrochemically Exfoliated β-Co(OH)2 Nanostructures for Enhanced Oxygen Evolution Electrocatalysis(2020)74 cited
- → High efficiency electrocatalyst of LaCr0.5Fe0.5O3 nanoparticles on oxygen-evolution reaction(2020)35 cited
- → In Situ Electrochemical Conversion of an Ultrathin Tannin Nickel Iron Complex Film as an Efficient Oxygen Evolution Reaction Electrocatalyst(2018)26 cited
- → Nd6Ir2O13 as an Efficient Electrocatalyst Boosts the Oxygen Evolution Reaction in Acidic Media(2022)25 cited
- → Electrocatalyst of RuO2 decorating TiO2 nanowire arrays for acidic oxygen evolution(2022)24 cited