RuII‐Mediated Hydrogen Transfer from Aqueous Glycerol to CO2: From Waste to Value‐Added Products
ChemSusChem2011Vol. 4(9), pp. 1311–1315
Citations Over TimeTop 15% of 2011 papers
Abstract
Aqueous glycerol was used as the hydrogen source for the reduction of CO(2) to the hydrogen carrier formic acid in the presence of the catalyst [RuCl(2)(PPh(3))(3)]. All intermediates were identified and characterized. Glycerol was converted into glycolic acid, HO-CH(2)-COOH, that was identified by using (1)H and (13)C NMR spectroscopy.
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