Singlet‐Oxygen Oxidation of 5‐Hydroxymethylfurfural in Continuous Flow
ChemSusChem2014Vol. 8(10), pp. 1648–1651
Citations Over TimeTop 10% of 2014 papers
Abstract
Singlet-oxygen oxidation of 5-hydroxymethylfurfural (5-HMF) was performed in continuous flow mode using rose Bengal as photosensitizer. The resulting butenolide (H(2) MF) was formed selectively in high yield. The procedure proved to be scalable and applicable to related bio-based furfurals. Furthermore, preliminary data show that H(2) MF can be readily isomerized thermally to 5-hydroxy-4-keto-pentenoic acid oligomers.
Related Papers
- → Visible Light-Induced and Singlet Oxygen-Mediated Photochemical Conversion of 4-Hydroxy-α-benzopyrones to 2-Hydroxy-3-oxo-2,3-dihydrobenzofuran-2-carboxamides/carboxylates Using Rose Bengal as a Photosensitizer(2020)61 cited
- → Photocatalytic trifluoromethoxylation of arenes and heteroarenes in continuous-flow(2020)29 cited
- → Unmodified Rose Bengal photosensitizer conjugated with NaYF 4 :Yb,Er upconverting nanoparticles for efficient photodynamic therapy(2020)26 cited
- → Partition of rose bengal anion from aqueous medium into a lipophilic environment in the cell envelope of Salmonella typhimurium: Implications for cell-type targeting in photodynamic therapy(1989)29 cited
- → Phosphazene-bound Rose Bengal: A novel photosensitizer for singlet oxygen generation(1991)25 cited