Fluorinated Alcohols as Activators for the Solvent‐Free Chemical Fixation of Carbon Dioxide into Epoxides
ChemSusChem2015Vol. 8(11), pp. 1845–1849
Citations Over TimeTop 10% of 2015 papers
Sandro Gennen, Margot Alvès, Raphaël Méreau, Thierry Tassaing, Bernard Gilbert, Christophe Detrembleur, Christine Jérôme, Bruno Grignard
Abstract
The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 into epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2 /epoxides coupling.
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