Spinel MnCo₂O₄ Nanoparticles Supported on Three‐Dimensional Graphene with Enhanced Mass Transfer as an Efficient Electrocatalyst for the Oxygen Reduction Reaction

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Abstract

The rational design of highly efficient and durable oxygen reduction reaction (ORR) catalysts is critical for the commercial application of fuel cells. Herein, three-dimensional graphene (3D-G) is synthesized by the template method, which used coal tar pitch as the carbon source and nano MgO as the template. Then, spinel MnCo₂ O₄ is in situ supported on the 3D-G by a facile hydrothermal method, giving MnCo₂ O₄ /3D-G. The resultant MnCo₂ O₄ /3D-G retains the multilayered mesoporous graphene structure where MnCo₂ O₄ nanoparticles are deposited on the inner walls of pores in the 3D-G. The catalyst MnCo₂ O₄ /3D-G shows high electrocatalytic activity with a half-wave potential of 0.81 V versus reversible hydrogen electrode, which is clearly superior to those of MnCo₂ O₄ /reduced graphene oxide (0.78 V), MnCo₂ O₄ /carbon nanotubes (0.74 V), MnCo₂ O₄ /C (0.72 V), and 20 wt % Pt/C (0.80 V). The electron transfer number of MnCo₂ O₄ /3D-G indicates a four-electron process of ORR. The durability test demonstrates that the MnCo₂ O₄ /3D-G catalyst has a much better durability than 20 wt % Pt/C. Our work makes an inspiring strategy to prepare high-performance electrocatalysts for the development of fuel cells.

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