Engineering Active Fe Sites on Nickel–Iron Layered Double Hydroxide through Component Segregation for Oxygen Evolution Reaction
Citations Over TimeTop 10% of 2019 papers
Abstract
Nickel-iron layered double hydroxide (NiFe LDH) is a promising oxygen evolution reaction (OER) electrocatalyst under alkaline conditions. Much research has been performed to understand the structure-activity relationship of NiFe LDH under OER conditions. However, the specific role of the Fe species remains unclear and under debate. Herein, based on DFT calculations, it was discovered that the edge Fe sites show higher activity towards OER than either the edge Ni sites or lattice sites. Therefore, a facile acid-etching method was proposed to controllably induce the formation of edge Fe sites in NiFe LDH, and the obtained sample exhibited higher OER activity. X-ray absorption near edge structure and extended X-ray absorption fine structure analyses further revealed that the interaction of the edge Fe species with Ni is believed to contribute to the enhancement of the OER performance. This work provides a new understanding of the structure-activity relationship in NiFe LDH and offers a facile method for the design of efficient electrocatalysts in an alkaline environment.
Related Papers
- → On the relationship between α-nickel hydroxide and the basic salts of nickel(1998)72 cited
- → Nickel hydroxide electrodeposition from nickel nitrate solutions: mechanistic studies(2001)66 cited
- → The electroformation of thick hydrous nickel hydroxide films through the application of periodic potential signals(1987)32 cited
- The Deactivation of Nickel Hydroxide to Hypophosphite Electrooxidation on a Nickel Electrode(2004)
- → Nickel-plated steel sheet(1998)