Recent Advances in the Chemistry of N5+, N5− and High‐Oxygen Compounds
Propellants Explosives Pyrotechnics2007Vol. 32(3), pp. 194–204
Citations Over TimeTop 10% of 2007 papers
Abstract
Abstract An overview of our work in the areas of polynitrogen and high‐nitrogen and high‐oxygen chemistry is given. Areas of interest include the synthesis and characterization of novel polynitrogen ions, such as N 5 + and N 5 − . Efforts are discussed to combine the N 5 + cation with energetic counter‐ions, such as N 3 − , NO 3 − , ClO 4 − , B(N 3 ) 4 − and P(N 3 ) 6 − . In the area of high‐oxygen carriers, complex nitrato anions were successfully combined with tetrazolium cations to yield CO/H 2 O balanced ionic liquids of interest for liquid monopropellants.
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