Long‐term performance of the Kiel carbonate device with a new correction scheme for clumped isotope measurements
Rapid Communications in Mass Spectrometry2014Vol. 28(15), pp. 1705–1715
Citations Over TimeTop 10% of 2014 papers
Anna Nele Meckler, Martin Ziegler, Isabel Pérez Millán, Sebastian F. M. Breitenbach, Stefano M. Bernasconi
Abstract
Our correction scheme eliminates the need for routine gas measurements, allowing for equal treatment of samples and standards with the Kiel device setup. While the PBL and standard data obtained over 15 months reveal variable mass spectrometer behavior, they provide a robust means of correction, yielding reproducible results from small carbonate samples in the long term.
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