Measurement of oxygen isotope ratios ( 18 O/ 16 O) of aqueous O 2 in small samples by gas chromatography/isotope ratio mass spectrometry
Rapid Communications in Mass Spectrometry2016Vol. 30(6), pp. 684–690
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Sarah G. Pati, Jakov Bolotin, Matthias S. Brennwald, Hans‐Peter E. Kohler, Roland A. Werner, Thomas B. Hofstetter
Abstract
The successful quantification of (18) O-kinetic isotope effects associated with enzymatic and chemical reduction of dissolved O2 illustrates how the proposed method can be applied for studying enzymatic O2 activation mechanisms in a variety of (bio)chemical processes.
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