Solidification point curves of binary acid mixtures. VII. Undecanoic to pentacosanoic acids
Journal of the American Oil Chemists Society1951Vol. 28(8), pp. 361–363
H. A. Schuette, R. M. Christenson, Unnsteinn H. Stefansson, Sallie Fisher, H. A. Vogel, Joseph Walker
Abstract
Summary The clearly defined inflections which characterize the solidification‐point diagrams of binary mixtures of the adjacent, straight‐chain acids of even number carbon atom content in the C 8 to C 16 area of the homologous series in question are not evident when an “odd” acid enters the picture. Pertinent diagrams for the adjacent odd‐odd acids, C 11 to C 25 , have been constructed. Although these diagrams have probably no known analytical application at the present, they have a potential one in the indirect determination and characterization of the higher alcohols oxidized to the corresponding acids.
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