Isomerization during hydrogenation. I. Oleic acid
Journal of the American Oil Chemists Society1955Vol. 32(7), pp. 400–405
Citations Over TimeTop 10% of 1955 papers
Abstract
Summary It was found that during the hydrogenation of octadecenoic acids, migration of the double bonds takes place equally in each direction. The positional isomers that are formed are composed of the 1∶2 equilibrium mixture of cis and trans . A partial hydrogenation‐dehydrogenation theory may be applied to explain the simultaneous formation of both positional and geometrical isomers.
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