Dehydrogenation of methyl 12‐hydroxystearate to methyl 12‐ketostearate with Raney nickel
Journal of the American Oil Chemists Society1966Vol. 43(3), pp. 125–127
Citations Over TimeTop 21% of 1966 papers
Abstract
Abstract Suitable conditions have been found for the dehydrogenation of methyl 12‐hydroxystearate to methyl 12‐ketostearate with Raney nickel. Crude reaction mixtures contained 95% product when analyzed by gas‐liquid chromatography (GLC). Isolated yields were 83%. Both catalyst concentration and type strongly influence the reaction. Laboratory‐made methyl 12‐hydroxystearate gave significantly better yields than commercial material, but satisfactory conversions were obtained from citrate‐free commercial material. The extent of the dehydrogenation was determined by hydrogen evolution and GLC. Synthetic and analytical techniques used in studying this reaction are discussed.
Related Papers
- → In situ X-ray diffraction study of dehydrogenation of MgH2 with Ti-based additives(2014)34 cited
- → Propane Dehydrogenation Catalysis of Titanium Hydrides: Positive Effect of Hydrogen Co-feeding(2021)5 cited
- → The catalytic effect of ZrCl4 on thermal dehydrogenation LiAlD4(2020)4 cited
- → Synthesis of Zn2TiO4 via solid-state method as a promising additive for dehydrogenation properties of NaAlH4(2023)3 cited
- → Dehydrogenation – Biological(2002)