Spectroelectrochemical Sensing Based on Attenuated Total Internal Reflectance Stripping Voltammetry. 3. Determination of Cadmium and Copper
Citations Over TimeTop 17% of 2004 papers
Abstract
The optical and electrochemical properties of metallic films on ITO surfaces resulting from deposition of copper and cadmium were monitored by stripping voltammetry-attenuated internal reflectance spectroscopy. The voltammetric or optical responses of both metals were examined with respect to solution conditions such as pH and presence of dissolved oxygen. The morphologies of these films were also examined using environmental scanning electron microscopy, and the microscopic electrodeposition patterns were found to influence the optical response. The wavelength dependence of the optical response of deposited copper was determined and compared with calculations; optimal performance was at 400 nm for copper. A linear calibration curve was obtained over a range of 1 × 10-7−1 × 10-4 M for copper and compared with that of cadmium. The simultaneous determination of cadmium and copper was demonstrated, and the mechanism of co-deposition is discussed.
Related Papers
- → Internal standards in differential pulse anodic stripping voltammetry(1991)8 cited
- → Tinplate anodic stripping voltammetry(1991)4 cited
- → Voltammetry(1986)2 cited
- Determination of Cadmium in Bean Paste by Linear Sweep Stripping Voltammetry(2012)
- Determination of Cadmium in Surface Water by Anodic Stripping Voltammetry(2010)