Titanium Sulfides as Intercalation-Type Cathode Materials for Rechargeable Aluminum Batteries
ACS Applied Materials & Interfaces2017Vol. 9(25), pp. 21251–21257
Citations Over TimeTop 10% of 2017 papers
Abstract
We report the electrochemical intercalation-extraction of aluminum (Al) in the layered TiS2 and spinel-based cubic Cu0.31Ti2S4 as the potential cathode materials for rechargeable Al-ion batteries. The electrochemical characterizations demonstrate the feasibility of reversible Al intercalation in both titanium sulfides with layered TiS2 showing better properties. The crystallographic study sheds light on the possible Al intercalation sites in the titanium sulfides, while the results from galvanostatic intermittent titration indicate that the low Al3+ diffusion coefficients in the sulfide crystal structures are the primary obstacle to facile Al intercalation-extraction.
Related Papers
- → Cooperative effects on the formation of intercalation sites(2004)44 cited
- → Preparation and Characteristics of Highly Expandable Graphite Intercalation Compounds by Two-Step Chemical Intercalation(2016)1 cited
- Effect of Structures of Intercalating Agent and Montmorillonite on Intercalation Modification of Montmorillonite(2011)
- Preparation of organic-intercalated montmorillonite by two-step intercalation(2003)
- Study on the intercalation of γ-PGA in montmorillonite(2011)