Promotional Effects of Cesium Promoter on Higher Alcohol Synthesis from Syngas over Cesium-Promoted Cu/ZnO/Al2O3 Catalysts
Citations Over TimeTop 10% of 2016 papers
Abstract
The promotional effects of a cesium promoter on higher alcohol (C2+OH) synthesis from syngas over Cs2O-Cu/ZnO/Al2O3 catalysts were investigated using a combined experimental and density functional theory (DFT) calculation method. In the presence of a cesium promoter, the C2+OH productivity increases from 77.1 to 157.3 g kgcat–1 h–1 at 583 K due to the enhancement of the initial C–C bond formation. A detailed analysis of chain growth probabilities (CGPs) confirms that initial C–C bond formation is the rate-determining step in the temperature range of 543–583 K. Addition of a cesium promoter significantly increases the productivities of 2-methyl-1-propanol, while the CGP values (C3* to 2-methyl-C3*) are almost unaffected. With the assistance of a cesium promoter, the CGPs of the initial C–C bond formation step (C1* to C2*) increase from 0.13 to 0.25 at 583 K. DFT calculations indicate that the initial C–C bond formation during syngas synthesis over the ZnCu(211) model surface is mainly due to the HCO + HCO coupling. In the presence of Cs2O, the stabilities of key intermediates such as HCO and H2CO are enhanced, which facilitates both HCO + HCO and HCO + H2CO coupling steps with lower activation barriers. In addition, Bader charge analysis suggests that the presence of cesium ions could facilitate nucleophilic coupling between HCO and H2CO for the initial C–C bond formation.
Related Papers
- → Catalytic investigation for Fischer–Tropsch synthesis from bio-mass derived syngas(2003)154 cited
- → Experimental microwave-assisted air gasification of biomass for syngas production(2022)37 cited
- → Methanol generation from bio-syngas: experimental analysis and modeling studies(2023)19 cited
- → Catalytic Conversion of Biomass-derived Syngas to Gasoline Range Hydrocarbons(2011)
- Assessment of the liquid phase methanol synthesis process: CO-rich vs. H{sub 2}-rich syngas(1994)