Chiral Ligand-Modified Metal Nanoparticles as Unique Catalysts for Asymmetric C–C Bond-Forming Reactions: How Are Active Species Generated?
ACS Catalysis2016Vol. 6(11), pp. 7979–7988
Citations Over TimeTop 10% of 2016 papers
Abstract
The use of chiral ligand-modified metal nanoparticles is a promising strategy for constructing active and robust asymmetric catalyst systems. A recent advance in such catalyst systems for C–C bond-forming reactions is highlighted, and the characteristics of the active species are discussed. Several studies suggested that a redox event between nanoparticles and reagents might be a key to generating active species from nanoparticles.
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