Fullerene−Porphyrin Constructs
Accounts of Chemical Research2004Vol. 38(4), pp. 235–242
Citations Over TimeTop 1% of 2004 papers
Abstract
Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene-porphyrin interaction underlies successful chromatographic separations of fullerenes, and there are promising applications in the areas of porous framework solids and photovoltaic devices.
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