Intermolecular Dynamics, Interactions, and Solvation in Ionic Liquids
Accounts of Chemical Research2007Vol. 40(11), pp. 1217–1227
Citations Over TimeTop 10% of 2007 papers
Abstract
Ionic liquids can simultaneously assume multiple solvent roles, because they are strongly polar and polarizable solvents and binary solutions and frequently contain very hydrophobic components. When the cation and anion functional groups are tuned appropriately, ionic liquids can be used as designer solvents for a broad range of applications. In this Account, we discuss our spectroscopic studies on the intermolecular interactions, dynamics, solvation, transport, and friction in ionic liquids, as compared with information obtained from macroscopic experiments including viscometry and calorimetry.
Related Papers
- → Biodegradable Ionic Liquids: Selected Synthetic Applications(2007)36 cited
- → Medium perturbations on the molecular polarizability calculated within a localized dipole interaction model(2002)39 cited
- → Parameters of average molecular polarizability in the MNDO, AM1 and PM3 methods(2001)10 cited
- → A quest for effective polarizability as a function of the radii(2021)1 cited
- → Graphite polarizability(1987)2 cited