Enantioselective oxidations of sulfides catalyzed by chloroperoxidase
Biochemistry1990Vol. 29(46), pp. 10465–10468
Citations Over TimeTop 1% of 1990 papers
Stefano Colonna, Nicoletta Gaggero, Amedea Manfredi, Luigi Casella, Michele Gullotti, Giacomo Carrea, Piero Pasta
Abstract
The chloroperoxidase-catalyzed and horseradish peroxidase catalyzed oxidations of sulfides by tert-butyl and other peroxides have been investigated. The former metal enzyme afforded the corresponding sulfoxides having R absolute configuration in up to 92% enantiomeric excess (ee), whereas the latter gave racemic products. The various factors that control the enantioselectivity of the oxygenation have been examined.
Related Papers
- → Citations Gone #Social: Examining the Effect of Altmetrics on Citations and Readership in Communication Research(2019)27 cited
- → Honoring Native American Code Talkers(2011)5 cited
- → From Attention to Citation, What and How Does Altmetrics Work?(2014)20 cited
- → Literature(1998)1 cited
- Susquehanna Chorale Spring Concert "Roots and Wings"(2017)