Synthesis of Peptide-Based Polymers by Microwave-Assisted Cycloaddition Backbone Polymerization
Biomacromolecules2006Vol. 8(2), pp. 327–330
Citations Over TimeTop 10% of 2006 papers
M. Van Dijk, Khalid Mustafa, Annemarie Dechesne, Cornelus F. van Nostrum, Wim E. Hennink, Dirk T. S. Rijkers, Rob M. J. Liskamp
Abstract
The optimized reaction conditions for the Cu(I)-catalyzed N-->C polymerization of azido-phenylalanyl-alanyl-propargyl amide to yield either high molecular weight linear polymers or medium-sized cyclic polymers is described. These reaction conditions will be applied to tailor the synthesis, properties, and structure of biologically relevant peptide-based biopolymers.
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