Novel Two-Dimensional Network Constructed from Polyoxomolybdate Chains Linked through Copper−Organonitrogen Coordination Polymer Chains: Hydrothermal Synthesis and Structure of [H2bpy][Cu(4,4‘-bpy)]2[HPCuMo11O39]
Crystal Growth & Design2004Vol. 5(1), pp. 257–260
Citations Over TimeTop 10% of 2004 papers
Abstract
A novel compound, [H2bpy][Cu(4,4‘-bpy)]2[HPCuMo11O39] (1), has been prepared under mild hydrothermal conditions and has been structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a novel two-dimensional network constructed from the interconnecting of polyoxomolybdate chains, {HPCuMo11O39}n4n-, and transition metal coordination polymer chains, {Cu(4,4‘-bpy)}nn+. It is the first example of a two-dimensional structure formed by a polyoxomolybdate chain through the linkage of a transition metal coordination polymer chain.
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