Two-Dimensional Square-Grid versus One-Dimensional Double-Stranded Networks: Counterion Regulation of the Formation of Macrocycle-Based Copper(I) Coordination Frameworks
Crystal Growth & Design2005Vol. 5(5), pp. 1707–1709
Citations Over TimeTop 10% of 2005 papers
Ki‐Min Park, Il Yoon, Joobeom Seo, Ji‐Eun Lee, Jineun Kim, Kyu Seong Choi, Ok‐Sang Jung, Shim Sung Lee
Abstract
A two-dimensional square-grid-shaped coordination polymer incorporating the dithiaoxa macrocycle (1), [Cu(1)CN]n (2), has been prepared by a self-assembly process involving the interaction of 1 with CuCN; the parallel reaction of 1 with CuI afforded the one-dimensional double-stranded coordination polymer [Cu(1)I]n (3).
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