An Aqua-Soluble Copper(II)−Sodium Two-Dimensional Coordination Polymer with Intercalated Infinite Chains of Decameric Water Clusters
Crystal Growth & Design2006Vol. 6(10), pp. 2200–2203
Citations Over TimeTop 10% of 2006 papers
Y.Y. Karabach, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Maximilian N. Kopylovich, Armando J. L. Pombeiro
Abstract
Self-assembly synthesis in water, at room temperature, with dinuclear copper triethanolaminate and aqua−sodium building blocks as well as benzene-1,2,4,5-tetracarboxylate linkers leads to the formation of an heteronuclear Cu−Na assembly with a two-dimensional metal−organic framework, providing the first example of an aqua-soluble copper-containing coordination polymer that hosts infinite chains of decameric water clusters (H2O)10 formed by quasiplanar cyclic water octamers with two pendent water molecules.
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