Flexible Ligand, Structural, and Topological Diversity: Isomerism in Zn(NO3)2 Coordination Polymers
Crystal Growth & Design2007Vol. 7(9), pp. 1863–1867
Citations Over TimeTop 10% of 2007 papers
Abstract
Two new metal−organic frameworks (MOFs), [Zn(p-BDC)(m-bix)0.5][Zn(p-BDC)(m-bix)]·H2O (1) and [Zn(p-BDC)(m-bix)] (2) (p-BDC = terephthalate, m-bix =1,3-bis(imidazol-1-ylmethyl)benzene), were synthesized and characterized structurally. Both of the MOFs feature the interpenetrated two-dimensional (2D) → three-dimensional (3D) network motifs. In particular, complex 1 represents the second example of intertwining of different 2D coordination motifs, and complex 2 shows a 3-fold parallel interpenetrated framework. In addition, the spectroscopic, thermal, and fluorescence properties of complexes 1 and 2 are investigated.
Related Papers
- → Copper and zinc complexes with 2,3-pyridinedicarboxylic acid or 2,3-pyrazinedicarboxylic acid: Polymer structures and magnetic properties(2008)49 cited
- → Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4(2003)15 cited
- → The Dependence of the Photographic Characteristic of a Polymer – zinc oxide – salt of Metal Photosensitive Compositions by the Polymer Structure Peculiarity(2012)1 cited
- Synthesis and structure of a Zinc(II) complex(2004)
- → ChemInform Abstract: A General Preparation of Polyfunctional Benzylic Zinc Organometallic Compounds.(2008)