Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins
Crystal Growth & Design2009Vol. 9(4), pp. 1960–1965
Citations Over TimeTop 10% of 2009 papers
Abstract
Seven new heterometallic frameworks have been synthesized with specific control over the metallic composition of each structure. Using Mn, Fe, Ni, V, and Pt metallated tetra-(4-carboxyphenyl)porphine (MTCPP) metalloligands and Zn and Co paddle-wheel building units, two series of heterometallic frameworks are assembled that maintain topology with changing metal composition.
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