Crystal Structure and Magnetic Properties of a New Two-Dimensional S = 1 Quantum Spin System Ni5(TeO3)4X2 (X = Cl, Br)
Citations Over TimeTop 10% of 2002 papers
Abstract
Two new transition-metal tellurium oxy-chlorides of the general formula Ni5(TeO3)4X2 (X = Cl, Br) have been isolated during the investigation of the ternary phase diagram NiO−NiCl2−TeO2. They crystallize in the monoclinic system, space group C2/c, and for the case of Ni5(TeO3)4Cl2 the unit cell is a = 19.5674(2) Å, b = 5.2457(1) Å, and c = 16.3084(1) Å, with β = 125.289(1)°. The structure is layered and built up of corner-connected [Ni5O17X2] entities, made of five nickel(II) octahedra associated by edge and face sharing. The tellurium(IV) atoms are fixed upon the nickel layers. Their lone pairs E and the halogen atoms are packed in a double layer perpendicular to the [010] direction. From the magnetic point of view, this system provides a new 2D S = 1 quantum spin system with antiferromagnetic superexchange interaction. The magnetic susceptibility shows anomalies pointing to magnetic ordering phenomena. The observed transition temperatures vary with the interlayer separation.
Related Papers
- → Spin susceptibility and superexchange interaction in the antiferromagnet CuO(2003)59 cited
- → Antiferromagnetic CsCrF 5 and canted antiferromagnetism in RbCrF 5 and KCrF 5(2017)5 cited
- → The Mechanism of Participation of Non‐Magnetic B‐Site Cations in the Superexchange in Spinels(1981)11 cited
- → Antiferromagnet-ferromagnet transitions in cobaltites(2012)3 cited
- → From double exchange to superexchange in charge ordering perovskite manganites(1998)