Metal−Organic Scandium Framework: Useful Material for Hydrogen Storage and Catalysis
Chemistry of Materials2005Vol. 17(23), pp. 5837–5842
Citations Over TimeTop 10% of 2005 papers
Josefina Perles, Marta Iglesias, M.A. Martı́n-Luengo, Ángeles Monge, C. Ruı́z-Valero, Natalia Snejko
Abstract
The 3D polymeric terephthalate of scandium has been synthesized and its structure solved by single-crystal XRD. It was obtained as a single phase and characterized and tested as a hydrogen and nitrogen adsorbent and heterogeneous catalyst as a redox agent in the oxidation of sulfides. The compound shows a BET area of 721 m2 g-1 with a high CBET = 7000. The high chemical and thermal stability and excellent hydrogen sorption properties make this compound a useful material for hydrogen storage.
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