Repetitive Functionalization of Water-Soluble Single-Walled Carbon Nanotubes. Addition of Acid-Sensitive Addends
Chemistry of Materials2007Vol. 19(14), pp. 3491–3498
Citations Over TimeTop 10% of 2007 papers
Abstract
A method has been developed for creating bulk quantities of water-soluble single-walled carbon nanotubes (SWNTs) that contain multifunctional, acid-sensitive addends. Utilizing aryl diazonium salts, the repetitive functionalization protocol can yield multifunctional SWNTs containing moieties that would not be stable to the harsh oleum functionalization conditions used previously. The presence of multifunctionality on the SWNTs has been confirmed using Raman spectroscopy, thermal gravimetric analysis, and X-ray photoelectron spectroscopy.
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