Remarkable Oxygen Intake/Release Capability of BaYMn2O5+δ: Applications to Oxygen Storage Technologies
Chemistry of Materials2010Vol. 22(10), pp. 3192–3196
Citations Over TimeTop 11% of 2010 papers
Teruki Motohashi, Taku Ueda, Yuji Masubuchi, Makoto Takiguchi, Tohru Setoyama, Kazunori Oshima, Shinichi Kikkawa
Abstract
Here, we report the remarkable oxygen intake/release capability of a double perovskite BaYMn2O5+δ. This oxide rapidly stores/releases a large amount of oxygen (>3.7 wt %) at moderate temperatures in a perfectly reversible manner. The oxygen intake/release behaviors of BaYMn2O5+δ are clearly beyond those of any conventional oxides in terms of the magnitude and sharpness of the processes. It also appeared that this oxide exhibits a significant catalytic activity for flameless combustions of hydrocarbons, presumably owing to its oxygen-storage ability.
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