Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
Chemistry of Materials2010Vol. 22(14), pp. 4120–4122
Citations Over TimeTop 1% of 2010 papers
Abstract
The new microporous metal−organic framework Cu[Ni(pdt)2] (pdt2− = pyrazine-2,3-dithiolate) is demonstrated to have an optical bandgap, p-type semiconductivity, and redox activity. The compound can be doped by using I2 as an oxidant, leading to an increase in conductivity by 4 orders of magnitude with retention of porosity.
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