Covalent Organic Frameworks with High Charge Carrier Mobility
Chemistry of Materials2011Vol. 23(18), pp. 4094–4097
Citations Over TimeTop 1% of 2011 papers
Shun Wan, Felipe Gándara, Atsushi Asano, Hiroyasu Furukawa, Akinori Saeki, Sanjeev K. Dey, Lei Liao, Michael W. Ambrogio, Youssry Y. Botros, Xiangfeng Duan, Shu Seki, J. Fraser Stoddart, Omar M. Yaghi
Abstract
Two types (imine and boronate) of covalent organic frameworks (COFs) having a porphyrin unit have been synthesized. The two highly crystalline porphyrin COFs (COF-366 and COF-66) display excellent chemical and thermal stability and are permanently porous. Two-dimensional extended layered structures of the two COFs demonstrate very high charge carrier mobility values (8.1 cm2 V−1 s−1).
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