Oxygen-Deficient Perovskite Sr0.7Y0.3CoO2.65−δ as a Cathode for Intermediate-Temperature Solid Oxide Fuel Cells
Chemistry of Materials2011Vol. 23(22), pp. 5037–5044
Citations Over TimeTop 10% of 2011 papers
Yan Li, Young N. Kim, Jinguang Cheng, J. A. Alonso, Zhiwei Hu, Yi‐Ying Chin, Tsuyoshi Takami, M. T. Fernández‐Díaz, Hong-Ji Lin, Chien‐Te Chen, L. H. Tjeng, Arumugam Manthiram, John B. Goodenough
Abstract
The oxygen-deficient perovskite Sr0.7Y0.3CoO2.65−δ contains Co2O6/2 (001) planes alternating with oxygen-deficient Co1O1.15-δ planes having 0.15−δ O4 oxygen in the plane capping tetrahedral site Co1. With ordering of the O4 atoms below 300 °C, the oxide exhibits n-type polaronic conduction associated with localized high-spin 3d electronic configurations on Co2+ in Co1 sites; a transition to itinerant-hole conduction occurs on disordering of O4 ions over the range 350 < T < 600 °C. Above 600 °C, Sr0.7Y0.3CoO2.65−δ is a mixed oxide-ion/electronic conductor exhibiting good activity for the oxygen-reduction reaction, which makes it a competitive cathode material for an intermediate-temperature solid oxide fuel cell.
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