Electrochemical Film Deposition of the Zirconium Metal–Organic Framework UiO-66 and Application in a Miniaturized Sorbent Trap
Citations Over TimeTop 10% of 2015 papers
Abstract
Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal–organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds.
Related Papers
- → Experimental investigation of adsorption of NO and SO2 on modified activated carbon sorbent from flue gases(2004)62 cited
- → Preparation of a Low-Cost K2CO3/Al2O3 Sorbent for CO2 Capture at Flue-Gas Operating Conditions(2013)5 cited
- → DEFINITION OPTIMAL MASS SORBENT “ECOLAN” FOR CLEANING WATER FROM OIL PRODUCTS(2012)
- The Efficiency for High-performance Sorbent to Sorb Heavy Metal Ions(2007)
- → HCl-Induced Hg0 Transformation over CuMn2O4 Sorbent(2022)