Superstructure Topologies and Host−Guest Interactions in Commensurate Inclusion Compounds of Urea with Bis(methyl ketone)s
Chemistry of Materials1996Vol. 8(8), pp. 1588–1591
Citations Over TimeTop 11% of 1996 papers
Abstract
Urea inclusion compounds containing aliphatic bis(methyl ketone) guests exhibit a common packing motif in which urea molecules turn about their 2-fold axes to form hydrogen-bonded tethers between guest molecules in adjacent channels. Because this motif is so reliable, it is possible to predict the superstructure topologies of the hydrogen-bonded networks of several bis(methyl ketone)/urea inclusion compounds and related systems. This constitutes an important step in the design of new ferroelastic inclusion compounds.
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