Gallium Imide, {Ga(NH)3/2}n, a New Polymeric Precursor for Gallium Nitride Powders
Chemistry of Materials1996Vol. 8(12), pp. 2708–2711
Citations Over TimeTop 10% of 1996 papers
Abstract
The efficient preparation of the new polymeric gallium imide {Ga(NH)3/2}n from the reaction between [Ga(NMe2)3]2 and NH3 at ambient temperatures is described. The gallium imide precursor is shown by TEM and XRD studies to yield upon pyrolysis a rare cubic/hexagonal variety of gallium nitride, GaN. Some control over the average particle size of GaN in the nanosized region is achieved by application of various pyrolysis schemes.
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