A New Phase of Oriented Mesoporous Silicate Thin Films
Chemistry of Materials1997Vol. 9(9), pp. 1962–1967
Citations Over TimeTop 1% of 1997 papers
Abstract
The syntheses and characterization of silicate/surfactant thin films with the structure P63/mmc is presented. The films are synthesized using a novel double-headed quaternary amine surfactant and can be grown either on mica or at the air−water interface. Films are shown to be crystalline and oriented with the c-axis perpendicular to the plane of the film. The films can be calcined to remove the surfactant and produce a mesoporous silicate material. Evidence is presented that suggests that films nucleate on hexagonally close packed surfactant micelles.
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