Functionalizable Self-Assembling Polydiacetylenes and Their Optical Properties
Chemistry of Materials1998Vol. 10(1), pp. 27–29
Citations Over TimeTop 10% of 1998 papers
Mongkol Sukwattanasinitt, X. Wang, L. Li, Xin Jiang, Jayant Kumar, Sukant K. Tripathy, Daniel J. Sandman
Abstract
The most versatile polydiacetylene system reported to date from the perspectives of systematic chemical modification and processability was obtained from γ-radiation polymerization of the alkoxycarbonylmethylurethanes of 9-(N-methyl-N-phenylamino)-5,7-nonadiyn-1-ol. These polymers self-assemble into an acentric array, and they are readily modified by functionalization of their dialkylaniline group. The modified polymers provide examples of materials with interesting second-order nonlinear optical properties and the first case of a rigid-rod polymer that exhibits photofabricated surface relief gratings.
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