Structure-Directing Role of Organoamine Ligands in the Self-Assembly of Novel Bimetallic Oxides
Chemistry of Materials1998Vol. 10(11), pp. 3294–3297
Citations Over TimeTop 10% of 1998 papers
Douglas Hagrman, Christopher J. Warren, Robert C. Haushalter, Candace T. Seip, Charles J. O’Connor, R.S. Rarig, Kenneth M. Johnson, Robert L. LaDuca, Jon Zubieta
Abstract
The introduction of dipodal nitrogen-donor ligands of varying extensions and the relative orientations of these donor groups have a profound influence on the microstructures of bimetallic copper molybdenum oxide phases. Tethered pyridyl donors yield Cu−Mo−O networks while pyrazine and pyrimidine are associated with three-dimensional Cu−Mo−O substructure frameworks with the organic components occupying well-defined channels, as illustrated alongside for [Cu2(pyrimidine)(Mo3O10)] (CUMO-6).
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