A Variable-Temperature Powder Neutron Diffraction Study of Ferroelectric Bi4Ti3O12
Chemistry of Materials1999Vol. 11(11), pp. 3359–3364
Citations Over TimeTop 10% of 1999 papers
Abstract
Powder neutron diffraction has been used to pinpoint the nature of the ferroelectric-paraelectric phase transition in Bi4Ti3O12. Below Tc (675 °C) the structure has been refined in orthorhombic space group B2cb [at 25 °C a = 5.4444(1) Å, b = 5.4086(1) Å, c = 32.8425(6) Å; at 650 °C a = 5.46183(5) Å, b = 5.44843(5) Å, c = 33.1742(3) Å]. At 800 °C the structure has been refined as tetragonal, I4/mmm a = 3.86334(2) Å, c = 33.2942(2) Å. Bond valence sum analysis of the coordination environments around each metal site as a function of temperature clearly demonstrate that the driving force for the ferroelectric transformation is the requirement for Bi in the perovskite-like A sites to optimize its bonding to neighboring oxygen atoms.
Related Papers
- → Polymorphism of BaTa2O6(1967)44 cited
- → Optical and structural properties of orthorhombic and tetragonal polymorphs of Cu2CdGeSe4(2018)6 cited
- → Strong ellipticity for tetragonal system in linearly elastic solids(2008)8 cited
- → Quest for an optoelectronic material: tetragonal SixGe1−x films(2002)3 cited
- Microwave Synthesis and Characterization of Both Cubic and Orthorhombic ZrW_(0.8)Mo_(1.2)O_8(2004)