Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes
ACS Catalysis2011Vol. 2(1), pp. 163–167
Citations Over TimeTop 20% of 2011 papers
Hao Peng, Aijun Lin, Yan Zhang, Honglai Jiang, Jiecong Zhou, Yixiang Cheng, Chengjian Zhu, Hongwen Hu
Abstract
An efficient method for the oxidation of benzylic sp3 C–H bond to produce ketones or esters using rhenium(V) complexes as catalysts has been developed. Moreover, the amination of benzylic sp3 C–H bond with NH2Ts in the presence of NBS has also been reported in moderate to good yields under the catalyst of rhenium(V)-based complexes.
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