High Performance Pt Monolayer Catalysts Produced via Core-Catalyzed Coating in Ethanol
ACS Catalysis2014Vol. 4(3), pp. 738–742
Citations Over TimeTop 10% of 2014 papers
Yu Zhang, Yu-Chi Hsieh, В.В. Волков, Dong Su, Wei An, Rui Si, Yimei Zhu, Ping Liu, Jia X. Wang, Radoslav R. Adžić
Abstract
Platinum monolayer core–shell nanocatalysts were shown to have excellent catalytic activities and stabilities. Usually, they are fabricated via electrochemical routes. Here, we report a surfactant-free, ethanol-based, wet chemical approach to coating Pd nanoparticles with uniform Pt atomic layers, inspired by aerobic alcohol oxidation catalyzed by the Pd cores. The as-prepared Pt monolayer electrocatalysts also exhibited high electrocatalytic performance toward the oxygen reduction reaction.
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