Catalytic Epoxidation Reaction over N-Containing sp2Carbon Catalysts
ACS Catalysis2014Vol. 4(5), pp. 1261–1266
Citations Over TimeTop 10% of 2014 papers
Wenjing Li, Gao Y, Wu-Lin Chen, Pei Tang, Weizhen Li, Zujin Shi, Dangsheng Su, Jianguo Wang, Ding Ma
Abstract
Nitrogen-doped graphene treated with ammonia under different temperatures was used as the catalysts for the epoxidation of trans-stilbene and styrene at 373 K. NG-800 (N-doped graphene treated at 800 °C for 8 h) performed the best and gave the highest recyclable catalytic activity for the epoxidation of trans-stilbene, with 95.8% conversion and 94.4% selectivity to trans-stilbene epoxide. The catalytic center has been identified with the reaction mechanism elucidated by DFT calculation.
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