Propane Dehydrogenation over Pt/TiO₂–Al₂O₃ Catalysts

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Abstract

This paper describes an investigation on understanding catalytic consequences of Pt nanoparticles supported on a TiO2–Al2O3 binary oxide for propane dehydrogenation (PDH). The TiO2–Al2O3 supports were synthesized by a sol–gel method, and the Pt/TiO2–Al2O3 catalysts were prepared by an incipient wetness impregnation method. Both as-prepared and post-experiment catalysts were characterized employing N2 adsorption–desorption, X-ray diffraction, Raman spectra, H2–O2 titration, temperature-programmed desorption, thermogravimetric analysis, temperature-programmed oxidation, transmission electron microscopy, and Fourier-transform infrared spectra of chemisorbed CO. We have shown that TiO2 is highly dispersed on Al2O3, and the addition of appropriate amount of TiO2 improves propylene selectivity and catalytic stability, which is ascribed to the electron transfer from partially reduced TiOx (x < 2) to Pt atoms. The increased electron density of Pt could reduce the adsorption of propylene and facilitate the migration of coke precursors from the metal surface to the support. The addition of TiO2, however, also increases the amount of strong acid centers on the supports and the excessive TiO2 addition might lead to a significant amount of coke formation. The electron transfer effect and the acid sites effect of TiO2 addition exert an opposite influence on catalytic performance. The trade-off between the electron transfer effect and the acid sites effect is studied by varying the amount of TiO2 loading. An optimal loading content of TiO2 is 10 wt %, which results in a higher propylene selectivity and a better stability.

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