Ruthenium Ion-Catalyzed Oxidation of Shenfu Coal and Its Residues
Energy & Fuels2008Vol. 22(3), pp. 1799–1806
Citations Over TimeTop 10% of 2008 papers
Yaoguo Huang, Zhi‐Min Zong, Zi‐Shuo Yao, Yuxuan Zheng, Jie Mou, Guangfeng Liu, Jing‐Pei Cao, Mingjie Ding, Keying Cai, Feng Wang, Wei Zhao, Z.-L. Xia, Lin Wu, Xian‐Yong Wei
Abstract
Shenfu coal (SFC), its liquefaction residue (RL), and carbon disulfide (CS2)/tetrahydrofuran (THF)-inextractable matter (RE) were subject to ruthenium ion-catalyzed oxidation to understand the differences in structural features among the above three samples. The results suggest that SFC is rich in long-chain arylalkanes and α,ω-diarylalkanes (DAAs) with carbon number of methylene linkage from 2 to 4 and that long-chain arylalkanes and DAAs are reactive toward hydroliquefaction and soluble in a CS2/THF mixed solvent, whereas highly condensed aromatic species in SFC show poor solubility in the CS2/THF mixed solvent.
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