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Indoor Secondary Pollutants from Household Product Emissions in the Presence of Ozone: A Bench-Scale Chamber Study

Environmental Science & Technology2006Vol. 40(14), pp. 4421–4428

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Hugo Destaillats, Melissa M. Lunden, Brett C. Singer, B. Coleman, Alfred T. Hodgson, Charles J. Weschler, William W. Nazaroff

Abstract

Ozone-driven chemistry is a source of indoor secondary pollutants of potential health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields for most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid, and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of secondary particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10(5) molecules cm(-3) were determined by an indirect method. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate chamber study, we exposed the dry residue of two products to ozone and observed the formation of gas-phase and particle-phase secondary oxidation products.

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Abstract

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